MA Wen-zhe（马文哲）1,2, SANG Sheng-bo（桑胜波）1,2, ZHANG Wen-dong（张文栋）1,2, HU Jie（胡杰）1,2,LI Peng-wei（李朋伟）1,2, LI Gang （李刚）1,2
(1. MicroNano System Research Center, Taiyuan University of Technology, Taiyuan 030024, China;2. Key Laboratory of Advanced Transducers and Intelligent Control System, Shanxi Province and Ministry of Education, Taiyuan 030024， China)
Abstract： Gold nanoparticles-dimethylsiloxane (AuNPs-PDMS) membrane is a novel composite material in biochemical technology and micro-electro-mechanical system (MEMS) research. It is widely used in biomedicine, biochemical detection and environmental protection due to its biocompatibility, elasticity and electric characteristics. In this paper, the characteristics of the composite membrane were described, and four methods for fabricating AuNPs-PDMS composite membranes were reviewed in detail. Besides, the advantages and disadvantages of the four methods were summarized, and the present problems and future researches were proposed.
Key words： gold nanoparticles (AuNPs); polydimethylsiloxane (PDMS); composite membrane
CLD number： TG146.3+1, O627.41 Document code： A
Article ID： 1674-8042(2013)02-0199-06 doi： 10.3969/j.issn.1674-8042.2013.02.023
References
[1] Lin C H, Jao W C, Yeh Y H, et al. Hemocompatibility and cytocompatibility of styrenesulfonate-grafted PDMS-polyurethane-HEMA hydrogen. Colloids and Surfaces B: Biointerfaces, 2009, 70 (1): 132-141.
[2] Agrawal S, Morarka A, Paknikar K M, et al. In situ synthesis of Au nanoparticles in 3D circular microchannels in PDMS using a simple and reliable molding method. Microelectronic Engineering, 2012, 90: 104-107.
[3] Mcdonald J C, Whitesides G M. Poly (dimethylsiloxane) as a material for fabricating microfluidic devices. Accounts of Chemical Research, 2002, 35(7): 491-499.
[4] Goyal A, Mohl M, Kumar A. In situ synthesis of catalytic metal nanoparticle-PDMS membranes by thermal decomposition process. Composite Science and Technology, 2011, 71(2) : 129-133.
[5] Thangawng A L, Ruoff R S, Swartz M A, et al. An ultra-thin PDMS membrane as a bio/micro-nano interface: fabrication and characterization. Biomedical Microdevices, 2009, (9): 587- 595.
[6] Unger M A, Chou H P, Thorsen T, et al. Monolithic microfabricated valves and pumps by multilayer soft lithography. Science, 2000, 288: 113 -116.
[7] Lee J N, Park C, Whitesides G M. Solvent compatibility of poly (dimethylsiloxane)-based microfluidic devices. Analytical Chemistry, 2003, 75: 6544-6554.
[8] Abbasi F, Mirzadeh H, Katbab A A. Modification of polysiloxane polymers for biomedical applications: a review. Polymer International, 2001, 50(12): 1279-1287.
[9] Velve-Casquillas G, Le Berre M, Piel M, et al. Microfluidic tools for cell biological research. Nano Today, 2010, 5(1): 28-47.
[10] ZHANG Qing, XU Jing-juan, LIU Yan，et al. In-situ synthesis of poly (dimethylsiloxane)-gold nanoparticles composite films and its application in microfluidic systems. Lab on a Chip, 2008, 8(2): 352-357.
[11] Trung N B, Yoshikawa H, Tamiya E, et al. Propitious Immobilization of gold nanoparticles on poly (dimethylsiloxane) substrate for local surface plasmon resonance based biosensor. Japanese Journal of Applied Physics, 2012, 51: 037001.
[12] SHI Chuan, CHENG Mo-jie, QU Zheng-ping, et al. Selective catalytic reduction of NO by methane over nano-silver catalysts. Journal of Fudan University (Natural Science), 2002, 41(3): 269-273.
[13] Fritsch D, Kuhr K, Mackenzie K, et al. Hydrodechlorination of chloroorganic compounds in ground water by palladium catalysts Part 1. Development of polymer-based catalysts and membrane reactor tests. Catalysis Today, 2003, 82: 105-118.
[14] Sato Y, Hosokawa K, Maeda M. Detection of non-cross-linking interaction between DNA-modified gold nanoparticles and a DNA-modified flat gold surface using surface plasmon resonance imaging on a microchip. Colloids and Surfaces B: Biointerfaces, 2008, 62(1): 71-76.
[15] Daniel M C, Astruc D. Gold nanoparticles: assembly, supra-molecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology. Chemical Reviews, 2004, 104: 293-346.
[16] Connor E E, Mwamuka J, Gole A, et al. Gold nanoparticles are taken up by human cells but do not cause acute cytotoxicity. Small, 2005, 1(3): 325-327.
[17] Tkachenko A G, Xie H, Coleman D, et al. Multi- functional gold nanoparticle-peptide complexes for nuclear targeting. Journal of the American Chemical Society, 2003, 125(16): 4700-4701.
[18] Simpson T R E, Parbhoo B, Keddie J L. The dependence of the rate of crosslinking in poly (dimethyl siloxane) on the thickness of coatings. Polymer, 2003, 44(17): 4829-4838.
[19] Scott A, Gupta R, Kulkarni G U. A simple water-based synthesis of au nanoparticle/PDMS composites for water purification and targeted drug release. Macromolecular Chemistry and Physics, 2010, 211(15): 1640-1647.
[20] Goyal A, Kumar A, Patra P K, et al. In situ synthesis of metal nanoparticle embedded free standing multifunctional PDMS films. Macromolecular Rapid Communications, 2009, 30(13): 1116-1122.
[21] WU Wen-ya, BIAN Zhi-ping, WANG Wei, et al. PDMS gold nanoparticle composite film-based silver enhanced colorimetric detection of cardiac troponin I. Sensors and Actuators B: Chemical, 2010,147 (1): 298-303.
[22] BAI Hai-jing, SHAO Min-ling, GOU Hong-lei, et al. Patterned Au/poly (dimethylsiloxane) substrate fabricated by chemical plating coupled with electrochemical etching forcell patterning. Langmuir, 2009, 25(17): 10402-10407.
[23] FAN Da-he, YUAN Shi-wei, SHEN Yong-miao. Surface modification with BSA blocking based on in situ synthesized gold nanoparticles in poly(dimethylsiloxane) microchip. Colloids and Surfaces B: Biointerfaces, 2010, 75 (2): 608-611.
[24] ZHEN Hai-xia, HUANG Bo-neng, HU Jun-man, et al. Synthesis and characterization of gold nanoparticles with various diameters. Acta Scientiarum Naturalium Universitatis Pekinensis, 2011, (5): 777-782.
[25] Musick M D, Keating C D, Lyon L A, et al. Metal films prepared by stepwise assembly. 2.construction and characterization of colloidal Au and Ag multilayers. Chemistry of Materials, 2000, 12(10): 2869-2881.
[26] Berry K R Jr, Russell A G, Blake P A, et al. Gold nanoparticles reducedin situand dispersed in polymer thin films: optical and thermal properties. Nanotechnology, 2012, 23(37): 375703.
[27] XIE Meng-ying, Aw K C, Langlois M, et al. Negative differential resistance of a metal-insulator-metal device with gold nanoparticles embedded in polydimethylsiloxane. Solid State Communications, 2012, 152(10): 835-838.
[28] Rosset S. Mechanical characterization of a dielectric elastomer microactuator with ion-implanted electrodes. Sensors and Actuators A: Physical, 2008, 144 (1): 185-193.
[29] Alici G, Punning A, Shea H R. Enhancement of actuation ability of Ionic-type conducting polymer actuators using metal ion implantation. Sensors and Actuators B: Chemical, 2011,157(1): 72-84.
[30] Niklaus M, Shea H R. Electrical conductivity and Young’s modulus of flexible nanocomposites made by metal-ion implantation of polydimethylsiloxane: The relationship between nanostructure and macroscopic properties. Acta Materialia, 2011, 59 (2): 830-840.
[31] YU Hai-hu, JIANG De-sheng. Spectroscopic studies on electrostatically felf-assembled gold nanoparticulate thin films. Spectroscopy and Spectral Analysis, 2002, 22(3), 511-514.
[32] WU Wen-ya, ZHONG Xiao-qin, WANG Wei, et al. Flexible PDMS-based three-electrode sensor. Electro Chemistry Communications, 2010, 12 (11): 1600-1604.
[33] ZHOU Fang, LU Ming, WANG Wei, et al. Electrochemical immunosensor for simultaneous detection of dual cardiac markers based on a poly (dimethylsiloxane)-gold nanoparticles composite microfluidic chip: a proof of principle. Clinical Chemistry, 2010, 56(11): 1701-1707.
[34] FAN Da-he, BI Lian-hua, TANG Fan, et al. L-Cysteine modified flexible PDMS-gold electrode for sensing ascorbic acid and copper. Sensors and Actuators B: Chemical, 2012, 161(1): 1124-1128.
[full text view]
